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研究業績



発表論文 2010-2014

2014年

  1. Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand
    Y. Tanabe, S. Kuriyama, K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Organometallics 33, 5295-5300 (2014).
  2. Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine
    T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 53, 11488-11492 (2014). [Highlighted in Angew. Chem.]
  3. Synthesis of Nitrogen Heterocycles via a-Aminoalkyl Radicals Generated from a-Silyl Secondary-Amines under Visible Light Irradiation
    K. Nakajima, M. Kitagawa, Y. Ashida, Y. Miyake, and Y. Nishibayashi
    Chem. Commun., 50, 8900-8903 (2014).
  4. Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides
    Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and Y. Nishibayashi
    Org. Biomol. Chem., 12, 5594-5596 (2014).
  5. Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand
    S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, N. Kamaru, K. Yoshizawa, and Y. Nishibayashi
    J. Am. Chem. Soc., 136, 9719-9731 (2014).
  6. Synthesis and Redox Properties of PNP Pincer Complexes Based on N-Methyl-4,4'-Bipyridinium
    Y. Miyake, K. Nakajima, Y. Higuchi, and Y. Nishibayashi
    Eur. J. Inorg. Chem., 4273-4280 (2014). [Highlighted at Cover Picture] [Cover Profile]
     
  7. Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst
    M. Shibata, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 50, 7874-7877 (2014). [Highlighted in Synfacts, 2014, 10]
  8. Unique Behavior of Dinitrogen-Bridged Dimolybdenum Complexes Bearing Pincer Ligand towards Catalytic Formation of Ammonia
    H. Tanaka, K. Arashiba, S. Kuriyama, A. Sasada, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Nature Communications, 5, 3737 (2014).
  9. Visible Light-Mediated Addition of a-Aminoalkyl Radicals to [60]Fullerene Using Photoredox Catalysts
    Y. Miyake, Y. Ashida, K. Nakajima, and Y. Nishibayashi
    Chemistry-A European Journal, 20, 6120-6126 (2014).
  10. ウェイド 有機化学 原書7版 上巻・下巻 (分担)
    中村浩之、岩本武明、斎藤慎一、柴田高範、田中健、長澤和夫、西林仁昭
    丸善出版 (2014).
  11. 遷移金属窒素錯体を用いた触媒的窒素固定反応に関する最近の進展
    西林仁昭、荒芝和也、結城雅弘
    有機合成化学協会誌, 72, 529-537 (2014).
  12. 常温常圧下での触媒的アンモニア合成反応開発の現状と将来展望
    田邊資明、西林仁昭
    日本エネルギー学会誌, 5月号, 386-392 (2014).

2013年

  1. Preparation and Reactivity of Dinitrogen-Bridged Dimolybdenum Tetrachloride Complex
    K. Arashiba, S. Kuriyama, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 49, 11215-11217 (2013).
  2. Preparation and Reactivity of Molybdenum-Dinitrogen Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand
    Y. Tanabe, S. Kuriyama, K. Arashiba, Y. Miyake, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 49, 9290-9292 (2013).
  3. Design and Preparation of Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands
    T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, K. Nakajima, and Y. Nishibayashi
    Chemistry-A European Journal, 19, 11874-11877 (2013).
  4. Copper-Catalyzed Nucleophilic Trifluoromethylation of Propargylic Halides
    Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 49, 7809-7811 (2013).
  5. Visible Light-Mediated Oxidative Decarboxylation of Arylacetic Acids into Benzyl Radicals: Addition to Electron-Deficient Alkenes by Using Photoredox Catalysts
    Y. Miyake, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 49, 7854-7856 (2013).
  6. Synthesis, Structure, and Reactivity of Group VI Metal Complexes Bearing Group IV Metallocenyldiphosphine Moieties and Pentamethylcyclopentadienyl Ligand
    T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics 32, 2007-2013 (2013).
  7. Ruthenium-Triggered Ring-Opening of Ethynylcyclopropanes Leading to [3+2] Cycloaddition with Aldehydes and Aldimines via Metal-Allenylidene Intermediates
    Y. Miyake, S. Endo, T. Moriyama, K. Sakata, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 52, 1758-1762 (2013). [Highlighted in Synfacts, 2013, 05]
  8. 遷移金属窒素錯体を用いた触媒的アンモニア合成法の最近の進展と今後の展望
    西林仁昭
    錯体化学会誌(Bull. Jpn. Soc. Coord. Chem.), 62, 21-25 (2013).
  9. Developing More Sustainable Processes for Ammonia Synthesis
    Y. Tanabe and Y. Nishibayashi
    Coord. Chem. Rev. (invitation), 257, 2551-2564 (2013).
  10. 穏和な条件下での触媒的アンモニア合成の開発を目指して
    田邊資明、西林仁昭
    ファインケミカル, 7月号, 42-48 (2013).
  11. 鉄錯体は「窒素固定能」を秘めていた!-常温常圧の窒素ガスからのアンモニア変換に光明
    西林仁昭
    化学, 6月号, 37-42 (2013).
  12. Cycloaromatization via Transition Metal-Comulenylidenes
    Y. Nishibayashi
    Transition-Metal-Mediated Aromatic Ring Construction; Ed. K. Tanaka, WILEY-VCH, 547-567 (2013).

2012年

  1. Iron-Catalysed Transformation of Molecular Dinitrogen into Silylamine under Ambient Conditions
    M. Yuki, H. Tanaka, K. Sasaki, Y. Miyake, K. Yoshizawa, and Y. Nishibayashi
    Nature Communications, 3, 1254 (2012).
  2. Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
    E. Kinoshita, K. Arashiba, S. Kuriyama, Y. Miyake, R. Shimazaki, H. Nakanishi, and Y. Nishibayashi
    Organometallics 31, 8437-8443 (2012).
  3. Direct sp3 C-H Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysis
    Y. Miyake, K. Nakajima, and Y. Nishibayashi
    Chemistry-A European Journal, 18, 16473-16477 (2012).
  4. Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides
    Y. Miyake, S. Ota, and Y. Nishibayashi
    Chemistry-A European Journal, 18, 13255-13258 (2012).
  5. Enantioselective Alkylation of b-Keto Phosphonates by Direct Use of Diaryl Methanols as Electrophiles
    M. Shibata, M. Ikeda, K. Motoyama, Y. Miyake, and Y. Nishibayashi
    Chem. Commun., 48, 9528-9530 (2012).
  6. Visible Light Mediated Addition of a-Aminoalkyl Radicals Generated from a-Silylamine to a,b-Unsaturated Carbonyl Compounds
    Y. Miyake, Y. Ashida, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 48, 6966-6968 (2012).
  7. Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Allylation of Propargylic Alcohols with a,b-Unsaturated Aldehydes
    M. Ikeda, Y. Miyake, and Y. Nishibayashi
    Organometallics, 31, 3810-3813 (2012).
  8. Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines
    M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics, 31, 2953-2956 (2012).
  9. Ruthenium- and Copper-Catalyzed Enantioseletive Propargylic Alkylation of Propargylic Alcohols with b-Keto Phosphonates
    K. Motoyama, M. Ikeda, Y. Miyake, and Y. Nishibayashi
    Organometallics, 31, 3426-3430 (2012).
  10. Synthesis and Reactivity of Hybrid Phophido- and Hydrosulfido-Bridged Diruthenium Complex: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands
    Y. Miyake, T. Moriyama, Y. Tanabe, S. Endo, and Y. Nishibayashi
    Organometallics, 31, 3292-3299 (2012).
  11. Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-type Pincer Ligands
    K. Arashiba, K. Sasaki, S. Kuriyama, Y. Miyake, H. Nakanishi, and Y. Nishibayashi
    Organometallics, 31, 2035-2041 (2012).
  12. Visible Light Mediated Utilization of a-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts
    Y. Miyake, K. Nakajima, and Y. Nishibayashi
    J. Am. Chem. Soc., 134, 3338-3341 (2012).
  13. Cooperative Catalytic Reactions Using Distinct Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation
    M. Ikeda, Y. Miyake, and Y. Nishibayashi
    Chemistry-A European Journal, 18, 3321-3328 (2012).
  14. Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Mild Reaction Conditions
    Y. Nishibayashi
    Dalton Transactions (Perspective, invitation), 41, 7447-7453 (2012). [Highlighted at Cover Picture]
  15. Transition Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles
    Y. Nishibayashi
    Synthesis (Review, invitation), 44, 489-503 (2012).
  16. Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement
    Y. Nishibayashi and S. Uemura
    Organoselenium Chemistry-Synthesis and Reactions; Ed. T. Wirth, WILEY-VCH, 287-320 (2012).
  17. (S,S)-FOXAP; Ferrocene, 1-[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-2-(diphenylphosphino)-, (2R)-
    Y. Nishibayashi
    Electronic Encyclopedia of Reagents for Organic Synthesis, RN01404 (2012).

2011年

  1. Remarkable Effect of Valence Electrons in Thiolato-Bridged Diruthenium Complexes toward Catalytic Dimerization of a-Methylstyrenes
    Y. Miyake, T. Moriyama, Y. Tanabe, G. Onodera, and Y. Nishibayashi
    Organometallics, 30, 5972-5977 (2011).
  2. Propargylic Substitution Reaction Catalyzed by Group IV (Ti, Zr, Hf)-Ru Heterobimetallic Complexes
    T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics, 30, 3194-3199 (2011).
  3. Copper-Catalyzed Enantioselective Propargylic Amination of Non-Aromatic Propargylic Esters with Amines
    A. Yoshida, G. Hattori, Y. Miyake, and Y. Nishibayashi
    Org. Lett., 13, 2460-2463 (2011). [Highlighted in Synfacts, 2011, 08]
  4. Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and their Application to Catalytic Dehydrogenation of Amine-Boranes
    T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics, 30, 2394-2404 (2011).
  5. Cooperative Catalytic Reactions Using Lewis Acid Catalysts and Organocatalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols Bearing Internal Alkyne with Aldehydes
    K. Motoyama, M. Ikeda, Y. Miyake, and Y. Nishibayashi
    Eur. J. Org. Chem., 2239-2246 (2011). [Highlighted at Cover Picture] [Spotlighted in Angew. Chem.]
  6. Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on Remarkable Role of Ferrocenyldiphosphine Ligands
    H. Tanaka, A. Sasada, T. Kouno, M. Yuki, Y. Miyake, H. Nakanishi, Y. Nishibayashi, and K. Yoshizawa
    J. Am. Chem. Soc., 133, 3498-3506 (2011).
  7. Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes
    A. Yoshida, M. Ikeda, G. Hattori, Y. Miyake, and Y. Nishibayashi
    Org. Lett., 13, 592-595 (2011).
  8. A Molybdenum Complex Bearing PNP-Type Pincer Ligands Leads to the Catalytic Reduction of Dinitrogen into Ammonia
    K. Arashiba, Y. Miyake, and Y. Nishibayashi
    Nature Chemistry, 3, 120-125 (2011). [Highlight at news & views in Nature Chem. 3, 95-96 (2011) by R. R. Schrock]
  9. 銅-アセチリド錯体を鍵中間体として経由する触媒反応の最近の進展
    服部 岳、三宅由寛、西林仁昭
    有機合成化学協会誌, 69, 1086-1098 (2011).
  10. Nitrogen Fixation: Nitrido Complexes Step up
    Y. Nishibayashi
    Nature Chemistry, 3, 502-504 (2011).
  11. Haber-Bosch法を超えるアンモニア合成
    西林仁昭
    化学, 7月号, 18-22 (2011).
  12. 窒素分子の活性化に基づく窒素固定法の開発
    西林仁昭
    不活性結合・不活性分子の活性化 (日本化学会 Current Review), 125-137 (2011).
  13. 窒素固定酵素ニトロゲナーゼに学ぶ次世代型窒素固定法の開発
    西林仁昭
    岩谷直治記念財団研究報告書, 34, 39-41 (2011).

2010年

  1. Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol
    M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics, 29, 5994-6001 (2010).
  2. Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand
    M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics, 29, 4148-4153 (2010).
  3. Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper-Allenylidene Complexes as Key Intermediates
    G. Hattori, K. Sakata, H. Matsuzawa, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
    J. Am. Chem. Soc., 132, 10592-10608 (2010).
  4. Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes
    M. Ikeda, Y. Miyake, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 49, 7289-7293 (2010). [Selected as Hot Paper] [Highlighted at Cover Picture] [Highlighted in Synfacts, 2010, 12]
  5. Intramolecular Edge-to-Face Aromatic p-p Interaction in Optically Active Ruthenium-Allenylidene Complexes for Enantioselective Propargylic Substitution Reactions
    K. Kanao, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
    Organometallics, 29, 2381-2384 (2010).
  6. Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols
    K. Kanao, Y. Miyake, and Y. Nishibayashi
    Organometallics, 29, 2126-2131 (2010).
  7. Copper-Catalyzed Diastereo- and Enantio-selective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine
    G. Hattori, Y. Miyake, and Y. Nishibayashi
    ChemCatChem, 2, 155-158 (2010).
  8. 銅触媒による不斉プロパルギル位置換反応の開発
    服部 岳、三宅由寛、西林仁昭
    化学工業, 702-710 (2010).
  9. 窒素固定酵素ニトロゲナーゼに学ぶ次世代型窒素固定法の開発
    西林仁昭
    岩谷直治記念財団研究報告書, 33, 109-111 (2010).
 


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