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研究業績



発表論文 1999年以前

1999年

  1. Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex
    Y. Nishibayashi, I. Takei, and M. Hidai
    Angew. Chem. Int. Ed., 38, 3047-3050 (1999).
  2. Extremely High-Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine)
    Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
    Organometallics, 18, 2291-2293 (1999).
  3. Iridium-Catalyzed Asymmetric Hydrosilylation of Imines by Chiral Oxazolinyl-Phosphine Ligands
    I. Takei, Y. Nishibayashi, Y. Arikawa, S. Uemura, and M. Hidai
    Organometallics, 18, 2271-2274 (1999).
  4. The Use of Chiral Diferrocenyl Diselenides for Highly Selective Asymmetric Intramolecular Selenocyclization
    H. Takada, Y. Nishibayashi, and S. Uemura
    J. Chem. Soc., Perkin Trans. 1, 1511-1516 (1999).
  5. Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Chiral Oxazolinylferrocenylphosphines and its Ru(II) Complex
    Y. Arikawa, M. Ueoka, K. Matoba, Y. Nishibayashi, M. Hidai, and S. Uemura
    J. Organomet. Chem., 572, 163-168 (1999).
  6. Sigmatropic Rearrangements of Organoselenium Compounds
    Y. Nishibayashi and S. Uemura
    Organoselenium Chemistry: A Practical Approach; Ed. T. G. Back, Oxford University Press, Oxford, 207-221 (1999).

1998年

  1. Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes
    S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai
    Inorg. Chem., 37, 6428-6434 (1998).
  2. Ruthenium-catalyzed Asymmetric Hydrosilylation of Ketones and Imine
    Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
    Organometallics, 17, 3420-3422 (1998).
  3. A Model for Protonation of Dinitrogen by Nitrogenase: Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear Complexes
    Y. Nishibayashi, S. Iwai, and M. Hidai
    J. Am. Chem. Soc., 120, 10559-10560 (1998).
  4. Bimetallic System for Nitrogen Fixation: Ruthenium-assisted Protonation of Coordinated N2 on Tungsten with H2
    Y. Nishibayashi, S. Iwai, and M. Hidai
    Science, 279, 540-542 (1998).
  5. 4級ホスホニウム塩のセレンディピティー的な効果 -不活性な塩化アリールの活性化と触媒活性の向上-
    西林仁昭
    化学,53, 63-64 (1998).
  6. 分子状水素錯体を用いた新規な水素化反応の開発
    干鯛眞信,西林仁昭
    Organometallic News, 121-124 (1998).
  7. 夢の常温での空中窒素固定法の開発に向けて,―窒素錯体と水素錯体との反応によるアンモニア合成―
    干鯛眞信,西林仁昭
    化学と工業,51, 1897-1899 (1998).
  8. Highly Selective Asymmetric Intramolecular Selenocyclization
    H. Takada, Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
    Phosphorus, Sulfur, and Silicon, 136-138, 629-632 (1998).

1997年

  1. Catalytic Asymmetric Sulfimidation
    H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura, C. P. Baird, T. J. Sparey, and P. C. Taylor
    J. Org. Chem., 62, 6512-6518 (1997).
  2. Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines, and Their Rhodium(I)-Complexes
    Y. Nishibayashi, K. Segawa, Y. Arikawa, K. Ohe, M. Hidai, and S. Uemura
    J. Organomet. Chem., 545 & 546, 381-398 (1997).
  3. Synthesis, Structures and Reactivities of Rhodium and Ruthenium Complexes with Novel Chiral Cyclopentadienyl-ferrocenyldiphenylphosphine Bidentate Ligand
    Y. Nishibayashi, I. Takei, and M. Hidai
    Organometallics, 16, 3091-3093 (1997).
  4. Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes
    Y. Nishibayashi, M. Yamanashi, Y. Takagi, and M. Hidai
    Chem. Commun., 859-860 (1997).
  5. Rhodium(I)-, Iridium(I)-, and Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as Chiral Ligands
    Y. Nishibayashi, J. D. Singh, Y. Arikawa, S. Uemura, and M. Hidai
    J. Organomet. Chem., 531, 13-18 (1997).
  6. ジルコニウムに配位する窒素分子の新しい反応
    西林仁昭
    Organometallic News, 95-96 (1997).
  7. Chiral Bis(oxazoline)-copper Catalyzed Enantioselective Imination of Sulfides
    H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
    Phosphorus, Sulfur, and Silicon, 120-121, 363-364 (1997).

1996年

  1. Palladium-catalyzed Homocoupling Reactions of Organic Tellurides
    Y. Nishibayashi, C. S. Cho, K. Ohe, and S. Uemura
    J. Organomet. Chem., 526, 335-339 (1996).
  2. Oxidative Addition of Diferrocenyl Dichalcogenides to [(η5-C5Me5)Ru(μ3-Cl)]4. Syntheses, Crystal Structures and Some Reactivities of Ferrocenylchalcogenolate-Bridged Diruthenium Complexes [(η5-C5Me5)RuCl(μ2-EFc)]2 (E=S, Se, Te; Fc=ferrocenyl)
    H. Matsuzaka, J.-P. Qü, T. Ogino, M. Nishio, Y. Nishibayashi, Y. Ishii, S. Uemura, and M. Hidai
    J. Chem. Soc., Dalton Trans., 4307-4312 (1996).
  3. Novel Asymmetric Catalytic Synthesis of Sulfimides
    H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
    Chem. Commun., 931-932 (1996).
  4. Iridium(I)-Catalysed Asymmetric Hydrosilylation of Ketones using Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand
    Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe, and S. Uemura
    Chem. Commun., 847-848 (1996).
  5. Enantioselective ortho-Lithiation of Substituted Ferrocenes
    Y. Nishibayashi, Y. Arikawa, K. Ohe, and S. Uemura
    J. Org. Chem., 61, 1172-1174 (1996).
  6. Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives, for the Rh(I)- and Ir(I)-Catalyzed Asymmetric Hydrosilylation
    Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, K. Ohe, and S. Uemura
    Organometallics, 15, 370-379 (1996).
  7. Palladium-catalyzed Cross-coupling Reactions between Organic Tellurides and Alkenes
    Y. Nishibayashi, C. S. Cho, and S. Uemura
    J. Organomet. Chem., 507, 197-200 (1996).
  8. Novel Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Reactions
    Y. Nishibayashi and S. Uemura
    Rev. Heteroatom Chem., MYU, Tokyo, 14, 83-118 (1996).

1995年

  1. Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Nucleophilic Ring-Opening of meso-Epoxides
    Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
    J. Chem. Soc., Perkin Trans. 1, 2871-2876 (1995).
  2. Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand for the Asymmetric Hydrosilylation of Ketones
    Y. Nishibayashi, K. Segawa, K. Ohe, and S. Uemura
    Organometallics, 14, 5486-5487 (1995).
  3. Allylic Amine Formation by Imination of Allylic Tellurides
    Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
    Tetrahedron Lett., 36, 6725-6728 (1995).
  4. Highly Selective Asymmetric Intramolecular Selenocyclisation
    Y. Nishibayashi, S. K. Srivastava, H. Takada, S. Fukuzawa, and S. Uemura
    J. Chem. Soc., Chem. Commun., 2321-2322 (1995).
  5. The First Example of Enantioselective Carbenoid Addition to Organochalcogen Atoms : Application to [2,3]Sigmatropic Rearrangement of Allylic Chalcogen Ylides
    Y. Nishibayashi, K. Ohe, and S. Uemura
    J. Chem. Soc., Chem. Commun., 1245-1246 (1995).
  6. High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic Rearrangement
    Y. Nishibayashi, T. Chiba, K. Ohe, and S. Uemura
    J. Chem. Soc., Chem. Commun., 1243-1244 (1995).
  7. Synthesis of [R,S;R,S]- and [S,R;S,R]-Bis[2-[1-(dimethylamino)ethyl]-ferrocenyl] Diselenides and Their Application to Asymmetric Selenoxide Elimination and [2,3]Sigmatropic Rearrangement
    Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
    J. Org. Chem., 60, 4114-4120 (1995).
  8. The First Example of Chirality Transfer in Allylic Telluroxides - Possible [2,3]-Sigmatropic Rearrangement
    T. Chiba, Y. Nishibayashi, J. D. Singh, K. Ohe, and S. Uemura
    Tetrahedron Lett., 36, 1519-1522 (1995).
  9. Stereo- and Chemo-Selectivity in Reduction of α-[Phenyl(or Methyl)seleno]- alkyl Aryl Ketones with Metal Hydrides
    I, Aoki, Y. Nishibayashi, and S. Uemura
    Bull. Chem. Soc. Jpn., 68, 337-340 (1995).
  10. Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation of Oxazolinylferrocenes
    Y. Nishibayashi, and S. Uemura
    Synlett, 79-81 (1995).

1994年

  1. Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using New Diferrocenyl Dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2 (E=S, Se, Te) as Chiral Ligands
    Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, and S. Uemura
    J. Chem. Soc., Chem. Commun., 1375-1376 (1994).
  2. Syntheses and Reactivities of Ferrocenyl Organyl Tellurides
    Y. Nishibayashi, T. Chiba, J. D. Singh, S. Uemura, and S. Fukuzawa
    J. Organomet. Chem., 473, 205-213 (1994).
  3. Synthesis of Chiral Diferrocenyl Diselenides and Their Application to Asymmetric Reactions
    Y. Nishibayashi, J. D. Singh, S. Uemura, and S. Fukuzawa
    Tetrahedron Lett., 35, 3115-3118 (1994).
  4. Dinuclear (η5-C5Me5)Ru Complexes Triply Bridged by Tellurium or Selenium Ligands - Syntheses and Characterisation of (η5-C5Me5)Ru(μ2-RTeTeR)(μ2-TeR)2Ru(η5-C5Me5) and [(η5-C5Me5)Ru(μ2-SeR)3Ru(η5-C5Me5)]Cl (R = Tol, Ph)
    H. Matsuzaka, T. Ogino, M. Nishio, M. Hidai, Y. Nishibayashi, and S. Uemura
    J. Chem. Soc., Chem. Commun., 223-224 (1994).

1993年

  1. Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones
    N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, and S. Uemura
    J. Org. Chem., 58, 3697-3702 (1993).
  2. Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides: Remarkable Effect of Added Triethylamine
    Y. Nishibayashi, N. Komatsu, K. Ohe, and S. Uemura
    J. Chem. Soc., Perkin Trans. 1, 1133-1138 (1993).
  3. Asymmetric [2,3]Sigmatropic Rearrangement
    via Chiral Selenoxide with Sharpless Oxidants
    N. Komatsu, Y. Nishibayashi, and S. Uemura
    Tetrahedron Lett., 34, 2339-2342 (1993).

1992年

  1. Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using R-(+)-Binaphthol
    N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
    Tetrahedron Lett., 33, 5391-5394 (1992).
  2. The First Example of Asymmetric Selenoxide Elimination: Application to the Synthesis of Chiral Allenes
    N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
    J. Chem. Soc., Chem. Commun., 46-47 (1992).


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